Police said the two-vehicle crash happened near Bovaird Drive and Dixie Road in Brampton at around 9:30 p.m.
Both drivers were taken to hospital in serious condition, police said.
Police said the SIU has been called in to investigate what happened.
The SIU is an independent agency that investigates the conduct of officers in incidents that have resulted in death, serious injury, or alleged sexual assault.
Several road closures were in place for the investigation.
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